(2,2′-Bipyridine-κ2 N,N′)bis­(4-formyl­benzoato-κO 1)copper(II)

نویسندگان

  • Jin-li Qi
  • Wei Xu
چکیده

The title mononuclear Cu(II) complex, [Cu(C(8)H(5)O(3))(2)(C(10)H(8)N(2))], is comprised of a Cu(II) cation, two 4-formyl-benzoate (L(-)) ligands and a 2,2'-bipyridine (bipy) ligand. The Cu(II) ion and bipy ligand lie on a crystallographic twofold rotation axis; the Cu(II) ion is coordinated by two N atoms from one bipy ligand and two O atoms from two different carboxyl-ate groups of two L(-) ligands, exhibiting effectively a distorted square-planar geometry. The complex mol-ecules are inter-linked to generate two-dimensional supra-molecular layers in the ab plane, formed by C-H⋯O hydrogen bonds, where the O acceptor is the O atom from the carboxyl-ate group not involved in coordination to the Cu(II) ion. The two-dimensional layers are stacked in a sequence via C-H⋯O hydrogen-bonding inter-actions where the formyl O atom acts as acceptor.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012